We develop Stone-Kleene relation algebras, which expand Stone relation algebras with a Kleene star operation to describe reachability in weighted graphs. Many properties of the Kleene star arise as a special case of a more general theory of iteration based on Conway semirings extended by simulation axioms. This includes several theorems representing complex program transformations. We formally prove the correctness of Conway's automata-based construction of the Kleene star of a matrix. We prove numerous results useful for reasoning about weighted graphs.